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Synthesis and characterization of indium intercalation compounds of molybdenum sulphoselenide

Identifieur interne : 000013 ( Main/Exploration ); précédent : 000012; suivant : 000014

Synthesis and characterization of indium intercalation compounds of molybdenum sulphoselenide

Auteurs : RBID : ISTEX:10853_1996_Article_BF00354667.pdf

Abstract

The synthesis, structure and properties of indium-intercalated compounds of molybdenum sulphoselenide, In1/3MoSxSe2−x (0≤x≤ 2) compounds were investigated. X-ray analysis shows that all these compounds possess layer-type structure with hexagonal symmetry. Studies of room-temperature magnetic susceptibility, thermoelectric power experiments and two-probe conductivity measurements in the temperature range 25–350 °C, confirmed that these are diamagnetic semiconductors with In1/3MoS2, In1/3MoS1.5Se0.5 and In1/3MoSxSe2–x (0≤x≤1.5) exhibiting n- and p-type conductivity, respectively. These results have been explained on the basis of existing band models. Thermal stability behaviour of these compounds in an air atmosphere and X-ray analysis of the oxidized product were also studied.

DOI: 10.1007/BF00354667

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<div type="abstract" xml:lang="eng">The synthesis, structure and properties of indium-intercalated compounds of molybdenum sulphoselenide, In1/3MoSxSe2−x (0≤x≤ 2) compounds were investigated. X-ray analysis shows that all these compounds possess layer-type structure with hexagonal symmetry. Studies of room-temperature magnetic susceptibility, thermoelectric power experiments and two-probe conductivity measurements in the temperature range 25–350 °C, confirmed that these are diamagnetic semiconductors with In1/3MoS2, In1/3MoS1.5Se0.5 and In1/3MoSxSe2–x (0≤x≤1.5) exhibiting n- and p-type conductivity, respectively. These results have been explained on the basis of existing band models. Thermal stability behaviour of these compounds in an air atmosphere and X-ray analysis of the oxidized product were also studied.</div>
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<abstract lang="eng">The synthesis, structure and properties of indium-intercalated compounds of molybdenum sulphoselenide, In1/3MoSxSe2−x (0≤x≤ 2) compounds were investigated. X-ray analysis shows that all these compounds possess layer-type structure with hexagonal symmetry. Studies of room-temperature magnetic susceptibility, thermoelectric power experiments and two-probe conductivity measurements in the temperature range 25–350 °C, confirmed that these are diamagnetic semiconductors with In1/3MoS2, In1/3MoS1.5Se0.5 and In1/3MoSxSe2–x (0≤x≤1.5) exhibiting n- and p-type conductivity, respectively. These results have been explained on the basis of existing band models. Thermal stability behaviour of these compounds in an air atmosphere and X-ray analysis of the oxidized product were also studied.</abstract>
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